隨著我國對可再生能源的開發和應用的不時深化開展, 應用畜禽糞便厭氧發酵產沼氣是一種十分有前景的能源應用途徑,但所產生的沼氣中都含有H2S氣體,由于它是一種腐蝕性很強的化合物,所以沼氣脫硫是沼氣應用的關鍵環節。
With the development and application of renewable energy in China, anaerobic fermentation of livestock and poultry manure to produce biogas is a very promising way of energy application. However, the biogas generated contains H2S gas. As it is a highly corrosive compound, biogas desulfurization is the key link of biogas application.
目前沼氣脫硫的辦法有兩大類,即物理化學法和生物法。物理化學法包括干法脫硫和濕法脫硫,已被普遍地應用且積聚了豐厚的經歷,但該辦法存在運轉費用高、投資大、產生二次污染等缺陷;而生物法以不需催化劑和氧化劑、不需處置化學污泥、少污染、低能耗、高效率、可回收單質硫等優點,惹起了人們的普遍關注。生物脫硫的安裝主要由生物脫硫塔和曝氣水箱構成,從厭氧罐內導出的沼氣由脫硫塔底部進入,脫硫循環水由泵打入脫硫塔頂,兩者在塔內逆向接觸反響,且塔內充有填料以供脫硫菌附著生長,同時也利于氣水平均散布以充沛接觸。生物脫硫分為3個階段 :
At present, there are two kinds of desulfurization methods for biogas, namely physical chemical method and biological method. Physicochemical methods, including dry desulfurization and wet desulfurization, have been widely used and accumulated rich experience, but they have some shortcomings such as high operating costs, large investment and secondary pollution. Biological methods have attracted widespread attention for their advantages of no catalyst and oxidant, no need to dispose of chemical sludge, less pollution, low energy consumption, high efficiency and recoverable elemental sulfur. 。 The installation of biological desulfurization is mainly composed of biological desulfurization tower and aeration tank. The biogas derived from anaerobic tank enters from the bottom of the desulfurization tower, and the circulating water of desulfurization is pumped into the top of the desulfurization tower. Both of them are in reverse contact and react in the tower, and the tower is filled with fillers for the attachment and growth of desulfurization bacteria, which is also conducive to the full contact of the gas level. Biological desulfurization can be divided into three stages:
1.H2S 氣體的溶解過程,即由氣相轉化為液相;
1. The dissolution process of H2S gas, i.e. from gas phase to liquid phase;
2.溶解后的H2S被微生物吸收,轉移至微生物的體內;
2. The dissolved H2S is absorbed by microorganisms and transferred to microorganisms.
3.進入微生物細胞內的H2S作為營養物被微生物合成、轉化和應用,從而到達去除H2S的目的。
3. H2S entering microbial cells is synthesized, transformed and applied by microorganisms as nutrients to remove H2S.
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